PPS
Material Type
Engineering Plastics
Material Full Name
Polyphenylene sulfide
Process Compatibility
Injection Molding, CNC Machining
Basic Properties
Property |
Parameter/Performance |
Remarks |
|---|---|---|
| Chemical Name | Polyphenylene Sulfide | Alternating benzene rings and thioether (-S-) backbone |
| Molecular Structure | Semi-crystalline thermoplastic (50-65% crystallinity) | Linear PPS (heat-resistant) vs. branched PPS (high-flow) |
| Density | 1.34~1.36 g/cm³ | 20% lighter than PEEK |
| Color | Natural amber (black/gray dyeable) | Opaque, high surface gloss |
| Mechanical Properties | ||
| – Tensile Strength | 65-85 MPa (dry) | Up to 200 MPa with glass fiber reinforcement |
| – Impact Strength | 5-8 kJ/m² (notched Izod) | Retains 80% strength at -40℃ |
| – Wear Resistance | PV limit >3 MPa·m/s | Superior self-lubrication vs. most engineering plastics |
| Thermal Properties | ||
| – HDT (1.82MPa) | 260-280℃ | Highest long-term service temp among engineering plastics |
| – Service Temperature | -40℃~220℃ (short-term 260℃) | UL RTI 220℃ (electrical) |
| Chemical Properties | ||
| – Chemical Resistance | Resists acids/alkanes/organic solvents below 200℃ | Only dissolves in concentrated HNO₃/H₂SO₄ |
| – Flammability | UL94 V0 (1.5mm, no additives) | LOI 44% (non-flammable) |
Processing Characteristics
Drying Essential:
- 140-150℃ for 3-4 hours (moisture <0.05%)
- Moisture causes splay marks/bubbles
Melt Temperature:
- 300-340℃ (crosslinks/degrades >380℃)
Mold Temperature:
- 130-160℃ (higher temps enhance crystallinity)
Special Requirements:
- Corrosion-resistant screws/barrels (H₂S release)
Common Application Areas
-
Automotive: EGR valves, ignition coil bobbins
-
Electronics: SMT connectors, 5G antenna covers
-
Industrial: Chemical pump impellers, high-temp filters
-
Appliances: Air fryer liners, hair dryer nozzles
PPS Modified Types
Type |
Characteristics |
Typical Applications |
|---|---|---|
| Neat Resin PPS | High purity, excellent electricals | IC substrates, insulating films |
| 40% Glass-Filled PPS | Flexural strength >250 MPa | Turbocharger components, pump housings |
| Carbon-Fiber PPS | Thermal conductivity 1.5 W/mK | Semiconductor thermal management parts |
| Wear-Resistant PPS | PTFE/graphite additives | Bearing cages, compressor vanes |
| Conductive PPS | Carbon black/fiber (10²-10⁴ Ω·cm) | Anti-static wafer carriers |
Advantages & Disadvantages
Advantages |
Disadvantages |
|---|---|
| Best-in-class heat resistance (220℃ long-term) | Brittle (requires reinforcement) |
| Inherently flame-retardant (halogen-free V0) | High processing energy (>300℃ melt) |
| Exceptional chemical resistance | Expensive (3-5× PA66 cost) |
Other Engineering Plastics Selection
POM Materials
PA Materials
PC Materials
PET Materials
PEEK Materials
FAQ Of PPS Materials
Visit our FAQ center for more questions.
Why does PPS require corrosion-resistant equipment?
- Releases trace hydrogen sulfide (H₂S) above 300℃
- Attacks standard steel screws/molds within 200 hours
Solutions: Use:
- Hastelloy® screws
- Titanium nitride-coated molds
What are critical considerations when processing PPS?
Pre-processing:
- Mandatory drying (140-150°C for 3-4 hrs, moisture <0.05%)
Injection Molding:
- Melt temperature: 300-340°C (higher for glass-filled grades)
- Mold temperature: 130-150°C (reduces internal stress)
Safety:
- Ventilation required (H₂S gas may release at degradation)
- Avoid copper molds (catalyzes decomposition)
How to choose between PPS and PTFE for high-temperature applications?
| Parameter | PPS | PTFE |
|---|---|---|
| Max. Temp. | 220-240°C | 260°C |
| Mechanical Strength | High (enhanced with fibers) | Low (requires fillers) |
| Wear Resistance | Good (can be lubricated) | Excellent (lowest CoF) |
| Processability | Moldable/injectable | Sintering only |
| Cost | Moderate (~60% of PTFE) | High |